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ChemicalProductsCASCatalogN6022,1208315-24-5,22:4n-6,N-786,2063-10-7,20:4(n-3),(+)-N0437,112835-48-0,N719,207347-46-4,N-[4-(334455667788991010,556050-49-8,N-98,957035-41-5,N-96,39847-41-1,N556,110816-78-9,N563,140686-92-6,N30,100511-49-7,N570,102552-17-0,Ethyl8-methoxy-2-oxo-2,3,4,5-tetrahydro-1H-benzo[b]azepine-4-carboxylate,912366-83-7,ETHYL8-METHOXY-2-OXO-2,3,4,5-TETRAHYDRO-1H-BENZO[B]AZEPINE-4-CARBOXYLATE,869363-13-3,IsoindolineHCLsalt,10479-62-6,1-Hydroxyethyl-1H-pyrazolo[3,4-b]pyrazine,118503-13-2,1-Hydroxyethyl-5-hydroxy-1H-pyrazolo[3,4-b]pyrazine,97205-51-1,UMiroliMus,851536-75-9,4-Cyanobutyricacid,39201-33-7,4-Cyanomethylbenzoicacid,83901-88-6,3-Cyanophenylacetonitrile,16532-78-8,2-ChlorophenylchloroforMate,2-(endo-5-Norbornene,125700-68-7,(3S,4R)-3-[(1R)-1-Hydroxyethyl]-4-[(1R)-1-methyl-3-diazo-3-(p-nitrobenzyloxycarbonyl)-2-oxopropyl]azetidin-2-one,137391-68-5,6-chlorouracil,PalladiuMonactivatedcarbon5Pd,2,6-Difluoro-3-aMinobenzoicacid,(),2-(Trifluoromethoxy)-4-bromobenzonitrile,1187983-97-6,4-TrifluoroMethoxyphenylaceticacid,2-Bromo-4-(Trifluoromethoxy)benzonitrile,1214334-83-4,5-bromo-2-(trifluoromethoxyl)benzonitrile,1210906-15-2,N/A,N/A,N-methyl-N,N-dioctadecyl-1-Octadecanaminiumchloride,13513-77-4,3-Cyano-1H-indole-5-carboxylicacid,889942-87-4,1-Bromo-3,4-difluorobenzene,348-61-8,Ethyltriphenylphosphoniumiodide,4736-60-1,BP-6,Colorlesstransparentliquid,2677-24-9,3-METHOXYCINNAMALDEHYDE,tert-butyl2-oxo-1-oxa-8-azaspiro[]decane-8-carboxylate,301226-27-7,5-(2-Chloroethyl)-1H-imidazole,13518-55-3,n/a,6997-79-1,4,4-(1,2-Ethenediyl)bis-benzenemethanol,101168-88-1,2-[4-(1-Methylethyl)phenyl]-6-phenyl-4H-thiopyran-4-one1,1-dioxide,174493-23-3,Tetrahydro-2-[4-(1-methylethyl)phenyl]-6-phenyl-4H-thiopyran-4-one1,1-dioxide,174493-22-2,L-3-Methoxyphenylalanine,1-[(4-Nitrophenyl)Methyl]pyrrolidine,133851-67-9,2-Cyanomethyl-N-methyl-N-phenyldithiocarbamate,,76926-16-4,(2,4,6-Trichloro-pyriMidin-5-yl)-aceticacidethylester,889944-72-3,4-((5-Chloro-2-((4-cyanophenyl)amino)pyrimidin-4-yl)oxy)-3,5-dimethylbenzonitrile,269055-05-2,2-(DiMethylaMino)benzotrifluoride,54672-14-9,4-PiperidineethanaMine,76025-62-2,1-(2,2-Diethoxyethyl)-3-methoxyurea,116451-49-1,Benzo[b]thiophen-6-yltrifluoromethanesulfonate,877264-48-7,Propanoicacid,2-[[(ethylthio)thioxoMethyl]thio]-2-Methyl-,881037-62-3,1-(2,4-Dichlorobenzyl)piperazinedihydrochloride,6270-11-7,6-(4-Methylpiperazin-1-yl)nicotinicacid,132521-70-1,Copper(II)IonophoreV,162316-51-0,5-Iodothiophene-2-carbaldehyde,5370-19-4,9-Bromo-6H-[1,2,4]triazolo[1,5-c]quinazolin-5-one,882517-92-2,1-(2,4-Dihydroxy-5-isopropylphenyl)ethanone,747414-17-1,Morpholine,4-(2-broMoethyl)-,hydrochloride,89583-06-2,Cinnamyltrimethylsilane,19752-23-9,3-(4-fluorophenyl)-5-Methyl-4-IsoxazoleMethanol,1018297-63-6,2-AMINO-2-(NAPHTHALEN-2-YL)ETHANOL,153875-87-7,4-[(pyridin-2-yl)carbonyl]-1H-pyrazol-5-aMine,931114-35-1,3-Bromo-4-iodothiophene,73882-41-4,2-Chloro-5-iodothiophene,28712-49-4,Diphenyldithioperoxyanhydride,5873-93-8,2,2-Dimethyl-5-[(4-methylphenyl)methylene]-1,3-dioxane-4,6-dione,15795-51-4,ethyl3-methylisothiazole-4-carboxylate,15901-51-6,(2-isopropyloxazol-4-yl)MethanaMinehydrochloride,15924-16-0,(3-AMino-1H-pyrazol-4-yl)(pyridin-2-yl)Methanone,96219-90-8,2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3-dioxane,4497-36-3,4-Cyclopropyl-2-(trifluoromethyl)pyrimidine-5-carboxylicacid,914201-19-7,1H-Pyrrolo[2,3-b]pyridine,6-chloro-4-nitro-1-[[2-(triMethylsilyl)ethoxy]Methyl]-,869335-22-8,4-(2-BroMoethyl)MorpholineHydrobroMide,42802-94-8,2-AMINO-2-(1-NAPHTHYL)ETHANOL,86217-42-7,4-Phenoxythiophene-2-carboxylicacid,81028-69-5,(trans,trans)-4-Propyl-[1,1-bicyclohexyl]-4-methanol,82562-85-4,trans-4-Propylcyclohexanemethanol,71458-06-5,4-(4-Methylphenyl)cyclohexanone,40503-90-0,1,3-Difluoro-5-pentylbenzene,121219-25-8,1,3-Difluoro-5-butyl-Benzene,1245649-46-0,4-Propyl-4-biphenylboronicacid,2,3-Difluoro-4-methyl-1,1-Biphenyl,864059-66-5,2,3-Difluoro-(4-propoxyphenyl)-Boronicacid,4-Ethynyl-4-propyl-1,1-Biphenyl,360768-57-6,4-Pentyl-4-biphenylboronicacid,4-Butyl-4-biphenylboronicacid,1-Ethynyl-4-(trans-4-pentylcyclohexyl)-Benzene,88074-72-0,Cokefluoride,2-(trifluoromethyl)-6-iodopyridine,100366-74-3,2-Bromo-3,5-dichloropyridine-4-carboxylicacid,N-Benzyl-(3S)-hydroxysuccinimide,101469-91-4,4-Chloro-2-(methylsulfonyl)pyridine,66154-70-9,N/A,RetinoicacidChemicalProperties,Uses,ProductionDermatologydrugsRetinoicacid(Tretinoin)iscommonlyusedindermatologydrugs,whichisthedepartmentofvitaminA(Victoriamethanol),canpromoteepithelialcellproliferationandupdates,andcaninhibittheproliferationanddifferentiationofkeratinocytes,,hyperkeratosisofdiseaseshaveacertaintherapeuticeffect,,ebaceousglands,,theproductalsohasanti-tumor,iasis,ichthyosis,follicularkeratosis,acne,lichenplanus,verrucousepidermalnevus,impetigo,vitiligo,lichenpsoriasis,thefaceofpityriasisalba,,ecrystal,,ethanol,acetone,chloroform,dichloromethane,,itisthermalinstability,suckupmoistureintheair,~180C,themeltingrangeofwhichismixedwithasmallamountofisomersis170~dermalhyperplasia,dfilmandpromotethedifferentiationofepidermalgranularlayercellsinthelatestageofthedifferentiationoftheepidermalcellsbyaffectingK10,e,,ithasmorethananumberoffunctionalpoints,havinginhibitoryeffectontheactivityofTyrosinehydroxylase,dopaoxidaseandtwohydroxyindoleoxidasethreecatalyzingenzyme,soastoreducetheformationofmelanin,idermalcellturnover,formofthestratumcorneumcelladhesion,,whileinhibitingtheformationofnewacne,,ithelialcells,,%,thebloodcanreachtheconcentrationpeakafter3hours,~/ml,afteroraladministrationof1mg/,,blooddrugconcentrationcanbeuptothesourcemetaboliclevelin7~,butthebloodconcentrationofthedrugissignificantlydecreased,whichmaybeduetotheinductionofcytochromeP450enzymes,,%ofmetabolitesisbyrenalexcretion,eticexistencewithvitaminAactivityofretinol(retinol),theapplicationofthedim,,theycanbedividedintothreegenerations:thefirstgenerationisclassofnonaromaticretinoid,,etretinateandacitretinastherepresentative;thethirdgenerationisclassofaromaticdimensionalAacid,aromaticmethylethylacetylene,acnevulgaris,especiallytheblackheadacnelesions,senile,fluorescentordrugskinatrophy,ichthyosisandvariousabnormalkeratinizationandpigmentexcessivecalmskindisease,(1)ointment:%%(2)gel:,urning,erythema,swelling,desquamation,crusting,pigmentincreaseordecrease,maymaketheskinlesionsmoreobvious,butalsoshowedthatthedrugisworking,,,(1)ThisdrugiscontraindicatedinpregnantwomenandpatientswiththeallergictotheTretinoin,theAderivativeofvitaminA,acuteorsubacutedermatitis,eczema,skindiseases.(2)Allergiccaution.(3)(4)Theproductshouldavoidcontactingwitheyesandothermucousmembranes(,mouth,nose,etc.).Donotuseinskinofwrinklinglocationandskinulceration.(5)Thesiteofusingmedicine,appearingthethingssuchasburning,itching,redness,,(6)Forthetreatmentofacne,thefirstfewweeksachecanbetemporarilyintensified,butshouldcontinuetotreatmorethan6weekstoreachthemaximumeffect.(7)Theproductshouldnotbeusedinlargeareas,thedailydosageshouldnotexceed20g.(8)Duringthecourseofmedication,donotuseotherdrugs,whichcancauseirritationanddamagetoskin,cosmeticsandcleaningagents,soasnottoaggravatetheskinreaction,resultinginincreaseindrugabsorptionandcausesystemicadversereactions.(9)Thesunavioletradiation,sotheproductismostappropriateintheeveningandbedtimeapplication,thetreatmentprocessshouldavoidthesun,(1)Retinoicacidcombiningwithlightsensitivedrugscanincreasetheriskofphotosensitiveness.(2)Retinoicacidcombiningwithsoapanddetergents,containingkeratolyticagents(suchasperoxybenzoicacid,Resorcinol,salicylicacid,sulfur,etc),ethanolpreparation,isotretinoincanaggravateirritationordrynesstoskin,andthereforemustbeusedwithcaution.(3)Retinoicacidcombiningwithsagocimetidine,cyclosporineanddiltiazem,verapamilandketoconazole,cancauseanincreaseinthebloodconcentrationofthedrug,andmayleadtoretinoicacidpoisoning.(4Retinoicacidcombiningwithpentobarbital,rifampicin,phenobarbital,cancausethebloodconcentrationoftheproductdecreasing.(5)TheproductwillaffectthelivercytochromeP450enzymesystem,resultinginchangesinbloodconcentrationsofthedrug.(6)Takingdrugsoryzanol,vitaminB1,vitaminB6withTretinoin,canmakeheadacherelievedordisappeared,gy,incluingthepharmacologicaleffects,pharmacokinetics,pharmacodynamics,indications,druginteractions,andadversereactionofthedrug,thesewereeditedbyYuriHuanginthechemcialbook(2015-09-24).Uses(1)Appliestoabnormaltyshiyongyupeofacne,fishphosphorusdiseaseandabnormalpsoriasis.(2)Resistancetoabnormalskindrugs.(3)Tretinoinmainlyaffectsthegrowthofbonesandepithelialmetabolism,canpromoteepithelialcellproliferationandupdates,andcaninhibittheproliferationanddifferentiationofkeratinocytes,,hyperkeratosisofdiseaseshaveacertaintherapeuticeffect,,ichthyosis,follicularkeratosis,acne,lichenplanus,verrucousepidermalnevus,impetigo,vitiligo,lichenpsoriasis,thefaceofpityriasisalba,gandanintermediateproductinbodilyvitaminA(dimethylalcohol),ethanol,acetone,chloroform,dichloromethane,,hygroscopicinair,,wound-healing,,hairfolliclekeratosis,acne,lichenplanus,verrucousepidermisnevus,ureophora,vitiligo,pityriasisrosea,andfacialpityriasissimplex,especiallyblackheadskinlesions,andsenile,sun-induced,ordruginducedskinatrophy,as,iummetabolism,itcanpromoteepitheliumcellgrowthandrenewal,anditcaninh,ithascertaincurativeeffectsondiseasesrelatedtokeratinization,,thickensthestratumgranulosumandstratumspinosum,andaffectsK1andK10keratinysisinlatestageepidermalcelldifferentiationtoinfluencethesiloxintosilymericproteinprocessandcross-linkedcoatingformation,thuspromotrmalitiestoremovekeratinplugs,thusbeingabletopreventandremoveacnelesions,andfollic,retinoicacidcanalsoaffectmelanogenesisofmelanocyteswithamulti-siteeffect,anditcaninhibittheactivityoftyrosinehydroxylase,dopaoxidase,dihydroxylindoleoxidase,andothertype-threecatalyticenzymes,se,%/kg,/,itwillbinduniversallywithserumprotein,,bloodc,butbloodconcentrationwillnoticeablydecrease,possiblyduetotheinductionofcytochromeP450,t,%ofthedrugisexcretedbythekidneys,itcanalsobeexcretedthroughbile,FeedadditivesPotassiumiodideisioniccompoundwhichiodineionsandsilverionscanformyellowprecipitatesilveriodide(whenexposestolight,itcandecompose,itcanbeusedtomakehigh-speedphotographicfilm),,itiscloselyrelatedtobasalmetabolismlivestock,itparticipatesinalmostallthemetabolismprocess,livestockiodinedeficiencycancausethyroidhypertrophy,basalmetabolicratedropps,,iodinerequirementsofhighproducingdairycows,yieldhensshouldincrease,,periodateeggscanreduc,duringthefatteningofanimals,thoughnotiodinedeficiency,inordertomakelivestockhypothyroidismstrong,enhancedanti-stress,maintainthehighestproductioncapacity,iodideisalsoadded,potassiumiodideastheiodinesourceisaddedtofeed,itcanpreventiodinedeficiencydisorders,promotegrowth,increaseeggproductionrateandreproductionrateandimprovefeedefficiency,theamountoffeedisgenerallyafewPPM,becauseofitsinstability,ironcitrateandcalciumstearate(generally10%)earpowerplantstoprovideorreservesiodinetablets,themainingredientispotassiumiodide,whennuclearpowerplantoccursdisasterandradiationleaks,thesurroundingresidentsshouldtakeiodinetablets,iodinecansa,withinfourhourscantakeeffect,butttemperatures(℃):128g/0℃;136g/10℃;144g/20℃;153g/30℃;162g/40℃;168g/50℃176g/60℃;192g/80℃;198g/90℃;206g/100℃PreparationPotassiumiodideismadebyabsorptionofiodineinpotassiumhydroxide:POTASSIUMIODIDE7613I2+6KOH5KI+KIO3+3H2OMostpotassiumiodate,KIO3,cesses,suchascarbonreductionorthermaldecompostionat600Ctoiodide:2KIO32KI+3O2Anothermethodofpreparationthatdoesnotinvolv,ferrosoferriciodide,Fe3I816H2O,isboiledwith15wt%potassiumcarbonatesolution:Fe3I816H2O+4K2CO38KI+4CO2+Fe3O4+16H2OAsimilarmethodisusedtopreparepotassiumbromide,discussedearlier(seePotassiumBromide.)Potassiumiodidecanbepreparedbyreactinghydriodicacidwithpotassiumbicarbonate:HI+KHCO3KI+CO2+%ofthesampleliquidpotassiumtest(IT-27)andiodidetest(IT-18),(FDA,,2000).Toxicity1::Itisgenerallyrecognizedassafe(USFoodandDrugAdministration,1985).%,granules,orpowder;strong,bitter,,alcohol,acetone,;inanimalandpoultryfeedstotheextentof10-30partspermillion;intablesaltasasourceofiodineandinsomedrinkingwater;,°,granuleorpowdermadebythereactionofi,alcohol,’scalotypeprocess,:Awhitecrystallinesolid,KI,withastrongbittertaste,solubleinwater,ethanol,andacetone;cubic;;°C;°lutionfollowedbyseparationfromtheiodate(whichisalsoformed)etriiodideionI3-,,inphotography,andalsoasanadditivet,(Anbex);Thyro-Block(Medpointe);Thyrosafe(RRRegistrations);Thyroshield(Fleming).Air<s:bariumchloride,cadmiumchloride,calciumchloride,cesiumchloride,lithiumchloride,silverchloride,rubidiumchloride,potassiumbromide,potassiumchloride,Potassiumiodide,rhodiumtetrabromide,sodiumbromide,sodiumchloride,andsodiumiodide[Mellor2,:164,].mofsporotrichosis,althoughneweragent:+ozone,trifluoroacetylhypofluorite,,diisopropylperoxydicarbonate,brominepentafluoride,,BrF3,FClO,metalticsalts,(/g),theprocesscanbe,/,ACS/USPgradehadLiandSbatPotassiumiodidePreparationProductsAndRawmaterialsRawmaterials365 手机在线FeedadditivesPotassiumiodideisioniccompoundwhichiodineionsandsilverionscanformyellowprecipitatesilveriodide(whenexposestolight,itcandecompose,itcanbeusedtomakehigh-speedphotographicfilm),,itiscloselyrelatedtobasalmetabolismlivestock,itparticipatesinalmostallthemetabolismprocess,livestockiodinedeficiencycancausethyroidhypertrophy,basalmetabolicratedropps,,iodinerequirementsofhighproducingdairycows,yieldhensshouldincrease,,periodateeggscanreduc,duringthefatteningofanimals,thoughnotiodinedeficiency,inordertomakelivestockhypothyroidismstrong,enhancedanti-stress,maintainthehighestproductioncapacity,iodideisalsoadded,potassiumiodideastheiodinesourceisaddedtofeed,itcanpreventiodinedeficiencydisorders,promotegrowth,increaseeggproductionrateandreproductionrateandimprovefeedefficiency,theamountoffeedisgenerallyafewPPM,becauseofitsinstability,ironcitrateandcalciumstearate(generally10%)earpowerplantstoprovideorreservesiodinetablets,themainingredientispotassiumiodide,whennuclearpowerplantoccursdisasterandradiationleaks,thesurroundingresidentsshouldtakeiodinetablets,iodinecansa,withinfourhourscantakeeffect,butttemperatures(℃):128g/0℃;136g/10℃;144g/20℃;153g/30℃;162g/40℃;168g/50℃176g/60℃;192g/80℃;198g/90℃;206g/100℃PreparationPotassiumiodideismadebyabsorptionofiodineinpotassiumhydroxide:POTASSIUMIODIDE7613I2+6KOH5KI+KIO3+3H2OMostpotassiumiodate,KIO3,cesses,suchascarbonreductionorthermaldecompostionat600Ctoiodide:2KIO32KI+3O2Anothermethodofpreparationthatdoesnotinvolv,ferrosoferriciodide,Fe3I816H2O,isboiledwith15wt%potassiumcarbonatesolution:Fe3I816H2O+4K2CO38KI+4CO2+Fe3O4+16H2OAsimilarmethodisusedtopreparepotassiumbromide,discussedearlier(seePotassiumBromide.)Potassiumiodidecanbepreparedbyreactinghydriodicacidwithpotassiumbicarbonate:HI+KHCO3KI+CO2+%ofthesampleliquidpotassiumtest(IT-27)andiodidetest(IT-18),(FDA,,2000).Toxicity1::Itisgenerallyrecognizedassafe(USFoodandDrugAdministration,1985).%,granules,orpowder;strong,bitter,,alcohol,acetone,;inanimalandpoultryfeedstotheextentof10-30partspermillion;intablesaltasasourceofiodineandinsomedrinkingwater;,°,granuleorpowdermadebythereactionofi,alcohol,’scalotypeprocess,:Awhitecrystallinesolid,KI,withastrongbittertaste,solubleinwater,ethanol,andacetone;cubic;;°C;°lutionfollowedbyseparationfromtheiodate(whichisalsoformed)etriiodideionI3-,,inphotography,andalsoasanadditivet,(Anbex);Thyro-Block(Medpointe);Thyrosafe(RRRegistrations);Thyroshield(Fleming).Air<s:bariumchloride,cadmiumchloride,calciumchloride,cesiumchloride,lithiumchloride,silverchloride,rubidiumchloride,potassiumbromide,potassiumchloride,Potassiumiodide,rhodiumtetrabromide,sodiumbromide,sodiumchloride,andsodiumiodide[Mellor2,:164,].mofsporotrichosis,althoughneweragent:+ozone,trifluoroacetylhypofluorite,,diisopropylperoxydicarbonate,brominepentafluoride,,BrF3,FClO,metalticsalts,(/g),theprocesscanbe,/,ACS/USPgradehadLiandSbatPotassiumiodidePreparationProductsAndRawmaterialsRawmaterialsChemicalProductsCASCatalogY11,1086639-59-9,Y134,849662-80-2,Y688,Y590,70386-06-0,Y105,12714-78-2,Y516,98043-60-8,90Y,yaaHprotein,YABBY3protein,YABBY2protein,YabGprotein,YabJprotein,YabMprotein,YACHTYARDWORKERS,YADANZIOSIDE-N,YADANZIOSIDE-G,95258-17-6,YADANZIOLIDE-C,95258-12-1,YADANZIOSIDE-E,95258-20-1,YADANZIOSIDE-B,YADANZIOSIDE-C,95258-16-5,YADANZIOSIDE-L,99132-97-5,YADANZIOSIDE-A,yadanziosideM,101559-99-3,yadanziosideF,95258-11-0,YacKprotein,YACONLEAFEXTRACT,YAEERYPIL,Yaf9,YaeQprotein,YAgar,Modified,YB-11,59527-65-0,YAH1protein,YajCprotein,YakAprotein,YAL048cprotein,YAM,Yamabusbitake(Hericiumerinaceus)Ext.,yakuchinone-A,78954-23-1,yakuchinoneB,yakton,YAMAFUKI,YAMAGUCHISARCOMAVIRUSONCOGENEHOMOLOG1,HUMAN,RECOMBINANT,YAMATAIMINE,67113-69-3,YAMAUDO,YAM-BOXTHORNNOODLE,Yam/Dioscorea-Inorganiccomposition(pleaseaskfordetailedinformation),Yam,Dioscoreavillosa,ext.,90147-49-2,105Y:ALPHA1-ANTITRYPSIN(359-374),YAMEXTRACT,YAL001-006protein,147336-78-5,Yanangine,105705-86-0,YALURONICACID,Yammexicano,YBCLprotein,Yamogeninacetate,YangdiMiewe,1795135-15-7,Yang-Gan-Wan,yam8protein,/mL(P),YANGONIN(PRIMARYSTANDARD),YANGONIN,500-62-9,YAMS,YANGTAOACTINIDIAROOTPLANTEXTRACT,YANHUSUO,,YANHUSUOPLANTEXTRACT,yanprotein,YanShouSengRongCapsules,Yantar-antitox-13C2,yanucamideB,yanucamideA,YAP1FusionProtein(WW),Yap17pprotein,yeast,138820-59-4,yAP1protein,124671-19-8,yAP2protein,YAP1,Recombinant,Human(Yes-AssociatedProtein1),yapsin3,YBHBprotein,YAP(Yes-associatedProtein,YAP65),YC170,59946-73-5,YC-1,170632-47-0,Yarivreagent,YARLOOPCLOVER,YAR1protein,(卤)-Yashabushiketol,YASglasses,YARROW(ACHILLEAMILLEFOLIUM)EXTRACT,Yarrowialipolyticaalkalineextracellularprotease,YarrowOil,YarrowFlower/HerbPowder,AchileaMillefolium,:1,AchileaMillefolium,YARROW,Yarrow,Achilleamillefolium,ext.,84082-83-7,Y-ART3,179465-88-4,YAU-17,60036-90-0,ycaCgpprotein,YAT1protein,YATSUSIRO,YccAprotein,Y2B8monoclonalantibody,References[1],,,ReversibleFormationandDecompositionofLiFClustersUsingTransitionMetalFluoridesasPrecursorsandTheirApplicationinRechargeableLiBatteries,AdvancedMaterials,2003,,736-739[2],,,,RadiationDosimeterUtilizingtheThermoluminescenceofLithiumFluoride,Science,1961,,333-334[3],,,,LithiumfluoridematerialpropertiesasappliedontheNIRCaminstrument,,4,2005[4],,,Low-TemperatureThermalPropertiesofLithiumFluorideContainingDislocations,PhononScatteringinCondensedMatter,1979,267-270[5],,,,Lowtemperaturesinteringofbariumtitanateceramicsassistedbyadditionoflithiumfluoride-containingsinteringadditives,JournaloftheEuropeanCeramicSociety,2010,,81-86[6],,,Molten-SaltReactorsHistory,Status,andPotential,1970,,107-117ChemicalPropertiesWhitepowderUsesTheimportantusesoflithiumfluorideareasfluxinglasses,vitreousenamelsandglazes;insolderingandweldingaluminum;,oflithiumhydroxideorlithiumcarbonatewithaqueoushydrofluoricacid:LiOH+HFLiF+,glasses,glazes,,,%[KwasnikinHandbookofPreparativeInorganicChemistry()AcademicPressVolIp2351963].LithiumfluoridePreparationProductsAndRawmaterialsRawmaterials2-MercaptobenzothiazoleChemicalProperties,Uses,ProductionChemicalPropertiesbeigeorlightyellowpowderwithafaintodourUsesantibacterial,:1,&,accelerantofvulcanization,andcontainedin“mercapto-mix.”Themostfrequentoccupationalcategoriesarethemetalindustry,homemakers,healthservicesandlaboratories,thebuildingindustry,uidsinthepotteryindustryPurificationMethodsCrystalliseitrepeatedlyfrom95%EtOH,orpurifyitbyincompleteprecipitationbydiluteH2SO4fromabasicsolution,followedbyseveralcrystallisationsfromacetone/H2Oor*,Au,Bi,Cd,Hg,Ir,Pt,andTl.[Beilstein27II233,27III/IV2709.]2-MercaptobenzothiazolePreparationProductsAndRawmaterialsRawmaterialsreactionsBenzaldehydecanbeslowlyoxidizedtobenzoicacidinair,(Cannizarroreaction)mayoccurundertheactionofconcentratedalkali:Heatingbenzaldehydeinthepresenceofcatalystofcyanideion,itwilloccurbimolecularcondensation:ChemicalPropertiesBenzaldehydeisthemain,,benzaldehydeundergoesautoxidationtoperbenzoicacid,,andcondensationwithaliphaticaldehydeslead,forexample,,forexample,inacidicmediainthepresenceofacatalyst,benzaldehydeisaby-productintheoxidation,inair,,:(i)purebenzaldehydeand(ii),perfume,,water,benzoicacid,benzylchloride,benzylalcohol,and/,ypressingthekernelsofpeaches,cherries,apricots,onprocesses,suchasgasolineanddieselengines,incinerators,(10%solution),,,likestainlesssteels,aluminum,aluminumbronze,nickelandnickel-basealloys,bronze,navalbrass,tantalum,titanium,,benzaldehydereleasesperoxybenzoicacidandbenzoicacidBenzaldehydeisusedinperfumes,soaps,foods,drinks,andotherproducts;asasolventforoils,resins,somecelluloseethers,celluloseacetate,,intheproductionofderivativesthatareemployedintheperfumeandflavorindustries,likecinnamaldehyde,cinnamylalcohol,cinnamicacid,benzylacetone,andbenzylbenzoate,intheproductionoftriphenylmethanedyesandtheacridinedye,benzoflavin;asanintermediateinthepharmaceuticalindustry,forinstance,tomakechloramphenicol,ephedrin,andampicillin,asanintermediatetomakebenzoin,benzylamine,benzylalcohol,mandelicacid,and4-phenyl-3-buten-2-one(benzylideneacetone),inphotochemistry,asacorrosioninhibitoranddyeingauxiliary,intheelectroplatingindustry,andintheproductionofagriculturalchemicalsOccurrencePresentascyanuricglucoside(amygdalin)inbitteralmond,peach,apricotkernelandotherPrunusspecies;amygdalinisalsopresentinvariouspartsofthefollowingplants:Sambucusnigra,Chrysophyllumarlen,Anacyclusofficinarnm,Anacycluspedunculatus,Davalliabrasiliensis,Lacumadeliciosa,Lacumamultifloraandothers;freebenzaldehydehasbeenreportedfoundinseveralessentialoils:hyacinth,citronella,orris,cinnamon,sassafras,,leek(raw)(AlliumporrumL.),crispbread,Camembert,GruyeredeComte,provolonecheeses,blacktea,saltedandpickledplum,cookedtrassi,Bantubeer,redsage(Texassage)(),arrack,scallop,hogplum(SpondiasmombinsL.),chekur(AlpiniasessilisKon.=Kaemferiagalanga)gchemicals,suchascinnamaldehyde,cinnamalalcohol,andamyl-andhexylcinnamaldehydeforperfume,soap,andfoodflavor;syntheticpenicillin,ampicillin,andephedrine;,apricots,cherries,,perfumery,cinnamicandmandelicacids,assolvent;,(burning),fixedoils,ether,andalcohol;tteralmond,peach,esandmayb,andcanbereadilymanufacturedbythechlorinationofmethylbenzeneandthesubsequenthydrolysisof(dichloromethyl)benzene:C6H5CH3+Cl2→C6H5CHCl2C6H5CHCl2+2H2O→C6H5CH(OH)2+2HClC6H5CH(OH)2→C6H5CHO+:;Recognition::sweet,oily,almond,cherry,nuttyandwoodyGener°&WaterReactionsOxidizesinairtoformbenzoicacid,,combustibleliquid,ehydeisoxidizedreadilybyairtobenzoicacid[Kirk-Othmer,3rded.,,1978,].IncontactwithstrongacidsorbasesBenzaldehydewillundergoanexothermiccondensationreaction[Sax,9thed.,1996,].Aviolentreactionwasobservedoncontactwithperoxyacids(peroxyformicacid)[DiAns,,Ber.,1915,48,].Anexplosionoccurredwhenpyrrolidine,Benzaldehyde,mals,–,gastrointestinalpain,gscausedtremor,bleedingfromsmallintestine,andanincreaseinurinevolume;inrats,,oral(guineapigs):1000mg/kgLD50value,oral(rats):1300mg/kgA500-mga,highboilingpoint,andlowvaporpressure,:Willbeeasilyignitedbyheat,(sewers,basements,tanks).Vaporexplosionhazardindoors,:Noreaction;ReactivitywithCommonMaterials:Noreactions;StabilityDuringTransport:Stable;NeutralizingAgentsforAcidsandCaustics:Notpertinent;Polymerization:Notpertinent;InhibitorofPolymerization:,usewater(maybeusedasablanket),alcohol,foam,bsequentfractionaldistillationfrombotanicalsources;synthetically,frombenzylchlorideandlimeorbyoxidationoftoluenePotentialExposureInmanufactureofperfumes,dyes,andcinnamicacid;assolvent;d,whereasinsid,roductresidues(vapors,liquid);observeallwarningsandprecautionslistedfortheproductShippingUN1990Benzaldehyde,Hazardclass:9;Labels:9—,bation(undernitrogenatreducedpressure)%Na2CO3(untilnomoreCO2isevolved),thenwithsaturatedNa2SO3andH2O,followedbydryingwithCaSO4,MgSO4orCaCl2.[Beilstein7IV505.]IncompatibilitiesThesubstancereactswithair,,oxidants,aluminum,iron,bases,andphenol,ea,,amines,alkalies,strongbases,;,cleaningcloths,clothing,sawdust,diatomaceousearth(kieselguhr),activatedcharcoal,,puncture,,light,heat,hotsurfacessuchashotpipes,sparks,openflames,nzaldehydePreparationProductsAndRawmaterialsRawmaterialscompanydirectorycompanysearchcompanynamesupplierlist3BScientificCorporation,BachemAG,HoneywellBurdick&JacksonInc.,BarkerIndustries,Inc.,BASFCorporation,BASFAktiengesellschaft,BASRFineChemicals,BaxendenChemicalsLtd.,Baymag,BDBiosciences,BeckmanCoulter,Inc.,BedoukianResearch,Inc.,Berry&Associates,Inc.,BETAPHARMA(SHANGHAI)CO.,LTD.,BetaPharma,Inc.,BethylLaboratories,Inc.,BharaviLaboratories(P)Ltd.,BiddleSawyerCorporation,BioBlocks,Inc.,BioCatalyticsInc.,BioconIndiaLimited,BIODESIGNInternational/OEMConcepts,Bio-Farma,BiofineInternationalInc.,BiogeneOrganicsInc.,BiologLifeScienceInstitute,BIOLOGOS,INC.,BiomedaCorporation,BIOMOLINTERNATIONAL,LP,BioQuadrantPharmaceuticalIntermediatesInc.,ABR-AffinityBioReagents,BiosearchTechnologies,Inc.,BioSourceInternational,Inc.,BioSpectra,Inc.,BiosynthAG,BIOTRENDChemikalienGmbH,BioVectradcl,BiozymeLaboratoriesInternational,Ltd.,Boaopharma,Inc.,BoehringerIngelheimGmbH,BoroChemSAS,BoronMolecularInc.,BOSCHESCIENTIFIC,LLC,BoulderScientificCompany,BridgeBioserviceLLC,BritishSaltLtd.,BrunoBockChemischeFabrikGmbH&Co.,XianBoojiePharmaceuticalandChemicalTechnologyCo.,Ltd,WuhanBrightFineChemicalsCo.,Ltd,ShanghaiBiosundrugCo.,Ltd,XianjuBelterCo.,Ltd,BeijingElementChem-techCompany,Beilstein(Wuhan)Science&TechnologyDevelopmentCo.,Ltd,XuzhouBestenchemTechnologyCo.,Ltd,BaodingJaheBiochemPharmaceuticalCo.,Ltd,ChengduCPBiochemCo.,Ltd,BeiliPharmRawMaterial(Suzhou)Co.,Ltd,SuzhouBECBiologicalTechnologyCo.,Ltd,ShanghaiJinheBio-TechnologyCo.,Ltd,NanjingBoerkaiChemicalCo.,Ltd,ShaanxiBaojiBaoyuChemicalCo.,Ltd,BeijingNayingcaiBiodegradationTechnologyCo.,Ltd,AnhuiBaishiChemicalCo.,Ltd,JinanBofaPharmaceuticalTechnologyCo.,Ltd,WujinBoyiChemicalFactory,BeijingChengyuSpecialityChemicalCo.,Ltd,FoshanBoerChemicalCo.,Ltd,JiangyinBoxinChemicalCo.,Ltd,BiogenScience&TechnologyCo.,Ltd,HubeiBlueskyChemicalIndustryCo.,Ltd,BeijingBeililaiDailyChemicalCo.,Ltd,BillikenInternationalHoldingLtd,HunanXiangdaBideChemicalCo.,Ltd,XiamenBokangBiologyTechnologyCo.,Ltd,GuangzhouJakerBioTechnologiesCo.,Ltd,HebeiBaochengChemicalCo.,Ltd,ChongqingBiocarePharmaceuticalCo.,Ltd,ChangzhouBaoKangPharmaceutical&ChemicalCo.,Ltd,BeijingXJFTBiotechDevelopmentCo.,Ltd,BeijingDilongChemicalCo.,Ltd,DynaInternational(Huaian)Co.,Ltd,HangzhouBmChemicalCo.,Ltd,ZhejiangBaiyunWeiyeChemicalStockCo.,Ltd,XianBiosepNaturalProductsCo.,Ltd,BeijingYinghuaLutongChemicalsCo.,Ltd,QingdaoBangliChemcialCo.,Ltd,,Ltd,ShanghaiQiuzhiyouBioscience&BiotechnologyCo.,Ltd,JiamusiBeixingOrganicChemicalCo.,Ltd,BestChemicalCompany,WeifngBaoshengChemicalindustryCo.,Ltd,JiashanBetaBiochemical&PharmaceuticalCo.,Ltd,BokaiChemicalCo.,Ltd,BayeeInternationalTradingCo.,Ltd,ChengduBayoupharmCo.,Ltd,BeijingFLYScienceandTechnologyCo.,Ltd,BayouhChemicalLtd,TianjinBaofengChemicalCo.,Ltd,HuangyanBotaiChemicalCo.,Ltd,BengbuJiucailuoChemicalCo.,Ltd,

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